Description of covalent bond in terms of generalized charges: potential and dissociation energy of homonuclear compound

The theory of generalized charges is an asymptotic approximation quantum mechanics for interatomic forces. It based on the model multicomponent electron gas, which extends Thomas–Fermi inhomogeneous gas to pair electronic states. present research takes in consideration participation field bonds. Herein, definition (GC) by means overlap integral wave functions valence electrons given, and properties GC are found out. Equations derived potential length a homopolar bond, dependence these parameters shown. dissociation energy diatomic molecule expressed terms nuclear charges, function multiplicity covalent angular momentum, vibrational binding electrons. parametrization rules substantiated priori calculation homonuclear molecules carried out against configuration bond charge. results compounds elements first four rows periodic table shown be satisfactory accuracy.